ハロゲンシステムズ株式会社 
テクノロジーとメリット

HSI’s amperometric analyzers have several unique advantages whether deployed in seawater as a TRO sensor, municipal drinking water chlorine analyzer, or wastewater chlorine sensor. The benefits of the Halogen Systems technology overcome many of the drawbacks of existing membrane amperometric and reagent feed systems commonly used.

High on the list of benefits are flow independence, self-cleaning electrodes, and lengthy calibration retention. These benefits are common to both the seawater-specific TRO series and the MP5 family. Both employ three-electrode amperometry using bare electrodes, an integrated cleaning system, and a built-in pH sensor. The integrated sensor package creates a durable, reliable, and cost-effective analyzer unlike anything else. See the list below, and click on the headers for additional information.

アンペロメトリックセンサーは、20ppmまでの全残留塩素レベルの測定も可能です。センサー先端の磁気結合ポンプは、電極に一定の一定流量を供給します。すべてのアンペロメトリックセンサーはフローセンシティブです。一定の流速、感度、S/N比を発生させることは、低いTRO検出レベルには適しています。内蔵ポンプはブラシレスDCモーターを使用しています。インペラはエンジニアリングポリマーで作られており、低摩擦と長寿命を実現しています。

Halogen uses a bare 3 electrode sensor, eliminating the need to replace clogged membranes or replenish electrolyte required by conventional amperometric sensors. This results in much lower maintenance requirements. In competing amperometric sensors, diluted electrolyte requires periodic sensor recalibration. Halogen’s technology needs no electrolyte and this allows their analyzers to hold calibrations much longer. For more information, see the Amperometric Technology page.

The Halogen chlorine sensors have a patented cleaning feature called SensiCLĒNE™.  Polymeric beads held within the sensor cap abrade the electrodes to minimize biofouling and remove calcium carbonate that typically deposits on the electrodes during operation in seawater. The polymeric beads are motivated by the flow from the internal pump. For more information, see the SensiCLĒNE™ page.

HSIの塩素センサーは試薬や廃棄物を必要としないため、メンテナンスコストや設置コストを削減することができます。Hach CL-17のような比色システムは、毎月試薬を補充し、ポンプや光学部品も定期的に交換する必要があります。これらはトラブルシューティングが困難であり、チューブはバイオファウリングのため交換が必要です。試薬や部品は、年間600ドル以上かかることもあり、人件費もかさみます。

Most competitor amperometric sensors often still require membranes and electrolyte and so do not reduce maintenance or water waste. Unlike the MP5™, at time of writing no other amperometric chlorine sensor is approved for NSF-61 usage in drinking water without a required waste stream.

Halogen’s MP5™ is the only amperometric chlorine sensor approved for NSF-61 usage. it can be installed as a side-stream unit, directly in a pipe, or submerged in a tank with no required waste stream.  This makes the MP5™ a good foundational component for drinking water applications such as remote reservoir monitoring, or dead-end water aging analytics.

HSI’s sensor measures five different parameters every minute: TRO, Oxidation Reduction Potential-ORP, pH, Salinity, and Temperature. The sensor uses these measurements to compensate for changes detected in the water source. While the pH of seawater does not change much, in brackish or freshwater, the pH can change drastically. Even when used in freshwater, the sensor can use conductivity measurement to compensate for signal changes. In addition, the temperature sensor allows the sensor to make compensation for all the parameters over -2 ° to 35 °C. These readings enable the sensor to operate and deliver accurate readings in virtually any water condition that a ship may encounter.

Our sensor’s electrochemical stabilization technique is unique. We use this technique to prevent the passivation of the electrodes. Passivation due to organic poisoning is a frequent problem with bare electrode amperometric sensors. This approach enables our chlorine sensor to stabilize and provide accurate readings, usually within one to two minutes. In contrast, our competitor’s bare electrode sensors require up to 24 hours after starting up for reliable readings.

Our sensor measures water at velocities from zero to 4.5 meters per second with less than a 5% change in signal. It can accomddddplish this thanks to its integrated pump. HSI has the only total residual chlorine sensor capable of direct insertion into a pipe.

廃液の流れをなくすことで、設置やメンテナンスを簡略化することができます。図2に示すホットタップバージョンは、配管からセンサーを取り外すことができ、配管から排水する必要がありません。ホットタップの設置方法では、サンプリングポンプ、切替バルブ、サンプリングライン、サンプルろ過の使用が不要となる。この方法により、設置コストを大幅に削減することができます。

Halogen uses a unique pH cartridge in its chlorine sensor system. The pH cartridge can withstand 10 bar to -0.7 bar pressures and rapidly wets if allowed to dry out, with its accuracy restored within 3 minutes. HSI is the only company with this type of pH electrode designed with these specifications in an amperometric chlorine analyzer. It does not require calibration for a year or affmore, and the cartridges last two years.

ハロゲン・システムズ社は、この新しい技術の研究開発により、5つの米国特許、2つの韓国特許、1つの中国特許を取得し、その他は申請中です。当社の塩素センサーは、ほぼすべての種類の水に含まれる全残留オキシダント(TRO)の測定において、既存技術の多くの限界を克服しました。

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